Oxalate chloride

An oxalate chloride or oxalato chloride is a mixed anion compound contains both oxalate and chloride anions.

Related compounds include oxalate fluorides[1] and oxalate bromides.[2]

Production

Oxalate chlorides may be produced by treating an oxalate salt with concentrated hydrochloric acid, or with a metal oxide dissolved in oxalic acid and hydrochloric acid solutions that are evaporated.[3]

List

name formula crystal space group cell volume density comment ref
Novgorodovaite Ca2(C2O4)Cl2•2H2O monoclinic I2/m a=6.936 b=7.382 c=7.443 β=94.3° loses water over 205°C; refract: α=1.500 β=1.545 γ=1.568 2V=71° (−) [4][5][6]
Ca2(C2O4)Cl2•7H2O triclinic P1 a = 7.3928 b = 8.9925 c = 10.484 α = 84.070 β = 70.95 γ = 88.545° 655.3 looses water at 25°C to 2H2O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−) [4][7]
Ca4(C2O4)3Cl2•8H2O dubious [4]
octakis(ethyl(dimethyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese [NH(CH3)2(C2H5)]8[Mn4Cl4Cr4(C2O4)12] monoclinic P21 a=13.8321 b=17.1042 c=20.4209 β=91.874° [8]
octakis(diethyl(methyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese [NH(CH3)(C2H5)2]8[Mn4Cl4Cr4(C2O4)12] monoclinic P21 a=14.1863 b=17.3479 c=20.4140 β=91.937° [8]
DABCO=1,4-diazabicyclo[2.2.2]octane; (DABCO-H+)2(DABCO-2H2+)[MnII(CH3OH)(Cl−)CrIII(oxalate)3]2−2(CH3OH) triclinic P1 a=8.093 b=9.070 c=19.574 α=83.471° β=89.875° γ=86.765° [9]
tetrakis(methylammonium) tetrakis(μ-oxalato)-octachloro-tetra-iron(iii) pentahydrate (MeNH3)2[Fe2(ox)2Cl4]·2.5H2O monoclinic P21/c a 10.7832 b 13.913 c 13.0578 β 104.060° [10]
methylammonium (μ-hydroxo)-bis(μ-oxalato)-dichloro-di-iron(iii) trihydrate MeNH3[Fe2(OH)(ox)2Cl2]·2H2O monoclinic Cc a=8.945 b=14.936 c=12.408 β=108.531° [10]
methylammonium oxonium bis(μ-oxalato)-(μ-oxo)-dichloro-di-iron(iii) dihydrate (H3O)(MeNH3)[Fe2O(ox)2Cl2]·3H2O orthorhombic Fdd2 a=14.914 b=23.507 c=9.261 [10]
DMF = dimethylformamide Fe2(C2O4)Cl4(DMF)4 triclinic P1 a=8.3919 b=8.7834 c=11.2881 α=70.248° β=71.993° γ=64.423° [11]
(dimim)2[Fe2Cl4(μ-ox)] ionic liquid [12]
L2=1,4-bis(imidazol-1-ylmethyl)benzene

bis(1,1'-(1,4-Phenylenebis(methylene))bis-1H-imidazol-3-ium) (μ2-oxalato)-tetrachloro-bis(oxalato)-di-iron(iii)

(H2-L2)2{Fe2(C2O4)3Cl4} triclinic P1 a=10.6758 b=10.7457 c=10.8774 α=113.219° β=109.138° γ=99.294° Z=1 1020.8 1.624 emerald [13]
tetramelaminium trioxalatoferrate(III) chloride dihydrate (C3H7N6)4{Fe(C2O4)3}Cl·2H2O monoclinic P21/c a=11.597 b=22.299 c=13.655 β=94.344° Z=4 3521 1.698 green [14]
methylammonium (μ-aqua)-tris(μ-chloro)-(μ-oxalato)-iron(iii)-potassium K(MeNH3)[Fe(ox)Cl3(H2O) monoclinic P21/m a=8.725 b=7.508 c=9.026 β=112.421° [10]
diethylmethylammonium [NH(CH3)(C2H5)2][FeCl2(C2O4)] monoclinic P21/c a=8.5125 b=10.775 c=14.9703 β=104.798° Z=4 1327.6 1.516 yellow; proton conductor [15]
bis(Tetramethylammonium) bis(μ2-oxalato)-tetrachloro-di-iron(iii) Me4N[FeIII(ox)Cl2] monoclinic P21/c a=7.9441 b=8.6093 c=17.8251 β=91.869 [16]
hexakis(Triethylammonium) hexakis(μ2-oxalato)-dodecachloro-hexa-iron(iii) Et3NH[FeIII(ox)Cl2] triclinic P1 a=10.9609 b=14.4602 c=14.5780 α=85.006° β=78.845° γ=83.0191 [16]
Triethylammonium (μ2-oxalato)-dichloro-iron(iii) Et3NH[FeIII(ox)Cl2] orthorhombic Fdd2 a=13.5878 b=37.972 c=10.8210 [16]
bis(Tetra-n-butylammonium) bis(μ2-oxalato)-tetrachloro-di-iron(iii) n-Bu4N[FeIII(ox)Cl2] monoclinic P21/c a=8.8836 b=15.1939 c=17.968 β=91.556° [16]
[Fe(oxalato)Cl2]3(3,5-dimethylpyrazole)2(3,5- dimethylpyrazolium)2 monoclinic C2/c a=19.527 b=11.867 c=19.429 β=115.66° Z=4 4058.20 1.684 green [17]
BETS = Bis(ethylenedithio)tetraselenafulvalene κ-BETS2[FeIII(C2O4)Cl2] black; metallic; [18]
bis(2-(5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-1-ium) bis(μ-oxalato)-tetrachloro-di-iron(iii) [BEDT-TTF][Fe(C2O4)Cl2] triclinic P1 a=8.896 b=11.401 c=11.427 α=112.062° β=103.775° γ=100.328° [19]
BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)[Fe(C2O4)Cl2](CH2Cl2) monoclinic P21/c a=8.858 b=11.012 c=14.932 β=103.39° [20]
tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate [Co(en)3]Cl(C2O4)·3H2O monoclinic C2/c a = 19.932 b = 9.3344 c = 19.088 β = 96.846° Z = 8 [21]
dpyam=di-2-pyridylamine; (μ2-Oxalato)-bis(di-2-pyridylamine)-dichloro-di-copper(ii) Cu2(dpyam)2(μ-C2O4)(Cl)2 triclinic P1 a=7.4122 b=8.6586 c=9.8002 α=87.900° β=72.022° γ=71.845° [22]
L = 3,5-dimethyl-1H-pyrazole Cu2(C2O4)(L)2Cl2(MeOH)2 triclinic P1 a=7.244 b=8.039 c=8.848 α=92.16° β=92.73° γ=96.21° [23]
bpy=bipyridine [Fe(bpy)3]2[NbO(C2O4)3]Cl·11H2O [24]
[Fe(bpy)3]2[NbO(2O4)3]Cl·12H2O orthorhombic P212121 a=14.975 b=21.708 c=22.351 Z=4 7266 1.530 dark red [24]
[Co(bpy)3]2[NbO(C2O4)3]Cl·11H2O monoclinic P21/c a=23.548 b=13.631 c=22.812 β=101.04 7187 1.536 orange red [24]
[Co(bpy)3]2[NbO(C2O4)3]Cl·12H2O orthorhombic P212121 a=15.103 b=22.075 c=22.386 Z=4 7463 1.495 brown [24]
[Ni(bpy)3]2[NbO(C2O4)3]Cl·11H2O monoclinic P21/c a=23.875 b=13.265 c=23.115 β=101.69 Z=4 7169 1.539 pink [24]
[Ni(bpy)3]2[NbO(C2O4)3]Cl·12H2O orthorhombic P212121 15.058 b=22.039 c=22.398 Z=4 7433 1.500 dark pink [24]
[Cu(bpy)3]2[NbO(C2O4)3]Cl·12H2O orthorhombic P212121 a=15.035 b=22.267 c=22.538 Z=4 7545 1.487 blue [24]
[Zn(bpy)3]2[NbO(C2O4)3]Cl·11H2O monoclinic P21/c 24.070 b=13.332 c=23.168 β=102.19 Z=4 7267 1.530 pink [24]
[Zn(bpy)3]2[NbO(C2O4)3]Cl·12H2O [24]
tris(Tetraethylammonium) tetrakis(μ3-sulfido)-(oxalato-O,O')-trichloro-cyano-tri-iron-molybdenum (Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)} monoclinic P21/n a=10.331 b=22.580 c=19.083 β=91.97° double cubane structure [25]
(μ2-Oxalato)-dichloro-bis(η6-p-cymene)-di-ruthenium [Ru2(μ-η4-C2O4)Cl2(η6-p-PriC6H4Me)2] monoclinic P21/n a=7.571 b=8.998 c=16.528 β=95.52° Z=2 1120.73 yellow [26]
chloro-(oxalato)-tris(pyridine)-rhodium mer-[Rh(C2O4)Cl(py)3] orthorhombic P212121 a=9.9999 b=12.0930 c=14.9368 Z=4 1806.2 1.705 yellow [27]
CHLOROPENTAAMMINECHROMIUM(III) BIS(OXALATO)PALLADATE [Cr(NH3)5Cl][Pd(C2O4)2] triclinic a = 3.225 b = 10.290 c = 11.390 α = 116.5° β = 97.9° γ = 91.2° 334.5 [28]
C(NH2)3Cd(C2O4)Cl(H2O)·H2O triclinic P1 a=6.8136 b=7.4890 c=10.0515 α=84.082° β=77.806° γ=88.813° band gap 3.76 eV [29]
SnC2O4Cl2 [30]
SnC2O4Cl2 . CuBr2 1/4EtOH green [30]
SnC2O4Cl2 . CuCl2 . H2O green [30]
SnC2O4Cl2 . CoBr2 1/8EtOH rose colour [30]
(Et4N)2C2O4 . SnCl2F2 . 2H2O: white [30]
(Me4N)2Sn(C2O4)Cl2 white [30]
(Et4N)2Sn(C2O4)Cl2 .(Et4N)2C2O4(SnCl4)2 . EtOH white [30]
Sn(C2O4)2 . 2[SnCl4 . (Pyridine)2] white [30]
(Et4N)2SnCl6 . (Et4N)2C2O4 . 2SnC2O4(OH)2 white [30]
(NH4)2Sb(C2O4)Cl3 orthorhombic P212121 a=8.6961 b=8.7844 c=13.5956 Z=4 1038.57 2.253 [31]
K2Sb(C2O4)Cl3 orthorhombic P212121 a=8.3966 b=8.6023 c=13,6342 Z=4 984.80 2.660 [31]
Rb2Sb(C2O4)Cl3 orthorhombic P212121 a=8.6769 b=8.8485 c=13.8014 Z=4 1059.64 3.053 birefringence 0.22@546 nm;NLO 2.1 × KH2PO4 [31]
Ba2Mn2Cl2(C2O4)3·4H2O monoclinic C2/c a=22.916 b=8.248 c=9.904 β=99.53° [32]
Ba2Fe2Cl2(C2O4)3·4H2O monoclinic C2/c a=22.798 b=8.297 c=9.849 β=99.90° [32]
Ba2Co2Cl2(C2O4)3·4H2O monoclinic C2/c a=22.675 b=8.230 c=9.757 β=100.00° purple [33][32]
BaCd(C2O4)1.5Cl(H2O)2 monoclinic C2/c a=23.101 b=8.253 c=10.040 β 99.14° band gap 4.53 eV [29]
La(C2O4)Cl monoclinic P21/n a=8.489 b=16.19 c=5.880 β=104.14° [34][35]
La(C2O4)Cl·3H2O [36]
Ce(C2O4)Cl [1]
Ce(C2O4)Cl·3H2O [36]
Pr(C2O4)Cl·3H2O stable to 163°C [36][1]
Nd(C2O4)Cl·3H2O stable to 167°C; dec 510° to NdOCl [36][1][37]
Sm(C2O4)Cl·3H2O stable to 174°C; dec at 347° to EuC2O4 [36][1]
Eu(C2O4)Cl·3H2O stable to 178°C [36][1]
Gd(C2O4)Cl·3H2O [36][38]
(Et4N)2Sn(C2O4)Cl2 . (Et4N)2C2O4(SnCl4)2 . EtOH [30]
[(Me4N)2C2O4SnCl4]2 . [(Me4N)2Sn(C2O4)2Cl2]2 . Sn(WO4)2 [30]
[Pt(HC2O4)Cl3]2− [39]
[Pt(HC2O4)(C2O4)Cl]2− [39]
K2[Pt(C2O4)Cl2]·H2O triclinic P1 a=7.136 b=7.308 c=10.130 α=86.75° β=74.58° γ=54.28° Z=2 457.7 3.27 [40][39]
[Pt(NH3)5Cl][Cr(C2O4)3] · 4H2O orthorhombic Pccn a=38.901 b=13.7267 c=14.9141 [41]
[Pt(NH3)5Cl][Fe(C2O4)3] · 4H2O orthorhombic Pccn a=39.0123 b=13.7232 c=14.8990 [41]
[Pt(NH3)5Cl][Co(C2O4)3] · 2H2O monoclinic P21 a=8.5158 b=12.6409 c=8.5726 β=105.000° [41]
lead chloride oxalate Pb2Cl2(C2O4) monoclinic C2/m a=5.9411 b=5.8714 c=9.4212 β=95.232° Z=2 327.26 5.82 dec 350°C to Pb, Pb5O2Cl6 and Pb3O2Cl2 [42]
Th4Cl4(C2O4)6•20H2O
Plutonium(III) oxalato chloride ?Pu(C2O4)Cl·3H2O blue; biaxial (−) [43]
Am(C2O4)Cl·3H2O monoclinic P21/n a=5.852 b=15.823 c=8.351 β=104.243° [44]

References

  1. ^ a b c d e f Mulokozi, A.M.; Weigel, F. (May 1973). "Differential thermal analysis studies of some rare earth metal oxalato halide-hydrates". Journal of Inorganic and Nuclear Chemistry. 35 (5): 1487–1492. doi:10.1016/0022-1902(73)80236-2.
  2. ^ Lugwisha, E. H. J.; Mulokozi, A. M.; Masabo, M. K. J. (November 1991). "Activation energy of thermal decomposition of LaC2O4Br". Journal of Thermal Analysis. 37 (11–12): 2567–2572. doi:10.1007/BF01912801. ISSN 0368-4466. S2CID 95356620.
  3. ^ Mulokozi, A.M. (June 1972). "The nature of products obtained from the reaction of hydrogen halides with some rare-earth metal oxalate hydrates". Journal of the Less Common Metals. 27 (3): 419–422. doi:10.1016/0022-5088(72)90075-6.
  4. ^ a b c Jones, Francis T.; White, Lawrence M. (July 1946). "The Composition, Optical and Crystallographic Properties of Two Calcium Oxalate-Chloride Double Salts". Journal of the American Chemical Society. 68 (7): 1339–1342. doi:10.1021/ja01211a075. ISSN 0002-7863. PMID 20991004.
  5. ^ Baran, Enrique J. (2014-12-17). "Review: Natural oxalates and their analogous synthetic complexes". Journal of Coordination Chemistry. 67 (23–24): 3734–3768. doi:10.1080/00958972.2014.937340. ISSN 0095-8972. S2CID 96163581.
  6. ^ Rastsvetaeva, R. K.; Chukanov, N. V.; Nekrasov, Yu. V. (2001). "[No title found]". Doklady Chemistry. 381 (1/3): 329–331. doi:10.1023/A:1012984825792. S2CID 91571345.
  7. ^ Piro, Oscar E.; Echeverría, Gustavo A.; González-Baró, Ana C.; Baran, Enrique J. (February 2018). "Crystal structure and spectroscopic behavior of synthetic novgorodovaite Ca2(C2O4)Cl2·2H2O and its twinned triclinic heptahydrate analog". Physics and Chemistry of Minerals. 45 (2): 185–195. doi:10.1007/s00269-017-0907-0. hdl:11336/87551. ISSN 0342-1791. S2CID 103745968.
  8. ^ a b Lozančić, Ana; Renka, Sanja; Barišić, Dario; Burazer, Sanja; Molčanov, Krešimir; Pajić, Damir; Jurić, Marijana (2023-06-19). "High Proton Conductivity of Magnetically Ordered 2D Oxalate-Bridged [Mn II Cr III ] Coordination Polymers with Irregular Topology". Inorganic Chemistry. 62 (24): 9418–9428. doi:10.1021/acs.inorgchem.3c00443. ISSN 0020-1669. PMID 37290133. S2CID 259118281.
  9. ^ Yoshitake, Masashi; Kubo, Kazuya; Endo, Toru; Noro, Shin-ichiro; Akutagawa, Tomoyuki; Nakamura, Takayoshi (2016-03-15). "Structural Design of Coordination Polymers Based on Manganese and Chromium Ions Bridged by Oxalate Ligands". Bulletin of the Chemical Society of Japan. 89 (3): 354–360. doi:10.1246/bcsj.20150373. ISSN 0009-2673.
  10. ^ a b c d Mastropietro, Teresa F.; Marino, Nadia; Munno, Giovanni De; Lloret, Francesc; Julve, Miguel; Pardo, Emilio; Armentano, Donatella (2016-11-07). "Selective Guest Inclusion in Oxalate-Based Iron(III) Magnetic Coordination Polymers". Inorganic Chemistry. 55 (21): 11160–11169. doi:10.1021/acs.inorgchem.6b01769. ISSN 0020-1669. PMID 27749048.
  11. ^ Zhang, Bin; Zhang, Yan; Kurmoo, Mohamedally (May 2007). "Preparation, crystal structure and magnetic property of a binuclear oxalate-bridged iron(III) compound: Fe2(C2O4)Cl4(DMF)4 (DMF=dimethylformamide)". Inorganica Chimica Acta. 360 (7): 2513–2517. doi:10.1016/j.ica.2006.10.028.
  12. ^ Cot, Sergi; Leu, Meike K.; Kalamiotis, Alexis; Dimitrakis, Georgios; Sans, Victor; de Pedro, Imanol; Cano, Israel (July 2019). "An Oxalate-Bridged Binuclear Iron(III) Ionic Liquid for the Highly Efficient Glycolysis of Polyethylene Terephthalate under Microwave Irradiation". ChemPlusChem. 84 (7): 786–793. doi:10.1002/cplu.201900075. hdl:10234/185443. ISSN 2192-6506. PMID 31943995. S2CID 196896383.
  13. ^ Wang, Lei; Wang, Wenqiang; Guo, Dong; Zhang, Ao; Song, Yaoguang; Zhang, Yiheng; Huang, Keke (2014). "Design and syntheses of hybrid supramolecular architectures: based on [Fe(C 2 O 4 ) 3 ] 3− metallotectons and diverse organic cations". CrystEngComm. 16 (24): 5437–5449. doi:10.1039/C4CE00357H. ISSN 1466-8033.
  14. ^ Wang, Lei; Wang, Wenqiang; Guo, Dong; Zhang, Ao; Song, Yaoguang; Zhang, Yiheng; Huang, Keke (2014). "Design and syntheses of hybrid supramolecular architectures: based on [Fe(C 2 O 4 ) 3 ] 3− metallotectons and diverse organic cations". CrystEngComm. 16 (24): 5437–5449. doi:10.1039/C4CE00357H. ISSN 1466-8033.
  15. ^ Burazer, Sanja; Molčanov, Krešimir; Šantić, Ana; Klaser, Teodoro; Wenger, Emmanuel; Pajić, Damir; Jagličić, Zvonko; Popović, Jasminka; Jurić, Marijana (2021-09-24). "Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility". Materials. 14 (19): 5543. Bibcode:2021Mate...14.5543B. doi:10.3390/ma14195543. ISSN 1996-1944. PMC 8509436. PMID 34639934.
  16. ^ a b c d Xu, Hong-Bin; Wang, Zhe-Ming; Liu, Tao; Gao, Song (2007-04-01). "Synthesis, Structure, and Magnetic Properties of (A)[Fe III (oxalate)Cl 2 ] (A = Alkyl Ammonium Cations) with Anionic 1D [Fe III (oxalate)Cl 2 ] - Chains". Inorganic Chemistry. 46 (8): 3089–3096. doi:10.1021/ic0618854. ISSN 0020-1669. PMID 17352466.
  17. ^ "Oxalate-Bridged Binuclear Iron (III) Complexes of 3, 5-Dimethylpyrazole Ligands: Synthesis, Structure, Spectral and Electrochemical Properties". International Journal of Chemical Engineering. 31 (2): 1179.
  18. ^ Zhang, Bin; Wang, Zheming; Zhang, Yan; Takahashi, Kazuyuki; Okano, Yoshinori; Cui, Hengbo; Kobayashi, Hayao; Inoue, Katsuya; Kurmoo, Mohamedally; Pratt, Francis L.; Zhu, Daoben (2006-04-17). "Hybrid Organic−Inorganic Conductor with a Magnetic Chain Anion: κ-BETS 2 [Fe III (C 2 O 4 )Cl 2 ] [BETS = Bis(ethylenedithio)tetraselenafulvalene]". Inorganic Chemistry. 45 (8): 3275–3280. doi:10.1021/ic051870q. ISSN 0020-1669. PMID 16602784.
  19. ^ Zhang, B.; Zhang, Y.; Wang, Z.; Yang, D.; Gao, Z.; Wang, D.; Guo, Y.; Zhu, D.; Mori, T. (2016). "[BEDT-TTF][Fe(C 2 O 4 )Cl 2 ]: an organic–inorganic hybrid semiconductive antiferromagnet". Dalton Transactions. 45 (42): 16561–16565. doi:10.1039/C6DT01845A. ISSN 1477-9226. PMID 27344978.
  20. ^ Zhang, Bin; Zhang, Yan; Gao, Zengqiang; Chang, Guangcai; Su, Shaokui; Wang, Dongwei; Guo, Yanjun; Zhu, Daoben (August 2014). "Synthesis, Crystal Structure, and Characterization of the Charge-Transfer Salt (BEDT-TTF)[Fe(C 2 O 4 )Cl 2 ](CH 2 Cl 2 ), {BEDT‐TTF = Bis(ethylenedithio)tetrathiafulvalene}". European Journal of Inorganic Chemistry. 2014 (24): 4028–4032. doi:10.1002/ejic.201402112. ISSN 1434-1948.
  21. ^ Jone Kirubavathy, S.; Velmurugan, R.; Parameswari, K.; Chitra, S. (November 2019). "Synthesis, characterization, single crystal XRD, in vitro antimicrobial and cytotoxicity study of tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate". Arabian Journal of Chemistry. 12 (7): 1581–1586. doi:10.1016/j.arabjc.2014.10.013.
  22. ^ Youngme, Sujittra; Cheansirisomboon, Achareeya; Danvirutai, Chanaiporn; Chaichit, Narongsak; Pakawatchai, Chaveng; van Albada, Gerard A.; Reedijk, Jan (September 2006). "Two new oxalato-bridged dinuclear copper(II) complexes with di-2-pyridylamine: crystal structures, spectroscopic and magnetic properties". Inorganic Chemistry Communications. 9 (9): 973–977. doi:10.1016/j.inoche.2006.05.022.
  23. ^ Bahemmat, Samira; Neumüller, Bernhard; Ghassemzadeh, Mitra (August 2015). "One-Pot Synthesis of an Oxalato-Bridged Cu II Coordination Polymer Containing an In Situ Produced Pyrazole Moiety: A Precursor for the Preparation of CuO Nanostructures". European Journal of Inorganic Chemistry. 2015 (24): 4116–4124. doi:10.1002/ejic.201500255. ISSN 1434-1948.
  24. ^ a b c d e f g h i Jurić, Marijana; Perić, Berislav; Brničević, Nevenka; Planinić, Pavica; Pajić, Damir; Zadro, Krešo; Giester, Gerald; Kaitner, Branko (2008). "Supramolecular motifs and solvatomorphism within the compounds [M(bpy) 3 ] 2 [NbO(C 2 O 4 ) 3 ]Cl·nH 2 O (M = Fe 2+ , Co 2+ , Ni 2+ , Cu 2+ and Zn 2+ ; n = 11, 12). Syntheses, structures and magnetic properties". Dalton Trans. (6): 742–754. doi:10.1039/B707937K. ISSN 1477-9226. PMID 18239829.
  25. ^ Demadis, Konstantinos D.; Chen, Sue-Jane; Coucouvanis, Dimitri (November 1994). "The synthesis, and properties of Fe/Mo/S clusters with MoFe3S4 cubane subunits, Mo bound bidentate oxalate ligands and terminal or bridging cyanide ligands. Structural characterization of (Et4N)3[(C2O4)(CN)MoFe3S4Cl3] and (Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)}". Polyhedron. 13 (22): 3147–3151. doi:10.1016/S0277-5387(00)83684-0. hdl:2027.42/31244.
  26. ^ Yan, Hong; Süss-Fink, Georg; Neels, Antonia; Stoeckli-Evans, Helen (1997). "Mono-, di- and tetra-nuclear p-cymeneruthenium complexes containing oxalato ligands". Journal of the Chemical Society, Dalton Transactions (22): 4345–4350. doi:10.1039/a704658h.
  27. ^ Vasilchenko, Danila; Tkachev, Sergey; Baidina, Iraida; Korolkov, Ilya; Berdyugin, Semen; Kozlova, Ekaterina; Kozlov, Denis (2018). "Preparation of a rhodium( iii ) cis -diaquacomplex by protic acid induced oxalate-release from mer -[Rh(C 2 O 4 )Cl(py) 3 ]". New Journal of Chemistry. 42 (24): 19637–19643. doi:10.1039/C8NJ04264K. ISSN 1144-0546.
  28. ^ Lagunova, V. I.; Filatov, E. Yu.; Plyusnin, P. E.; Komarov, V. Yu.; Martynova, S. A.; Korenev, S. V. (April 2021). "Synthesis and Thermal Properties of Double Complex Salt: Chloropentaamminechromium(III) Bis(Oxalato)Palladate". Journal of Structural Chemistry. 62 (4): 555–562. doi:10.1134/S0022476621040065. ISSN 0022-4766. S2CID 235374161.
  29. ^ a b Xu, Wei; Ma, Liang; Lv, Yi-Lei; Ma, Si-Yu; Liu, Wenlong; Guo, Sheng-Ping; Tang, Ru-Ling (2023-12-19). "C(NH 2 ) 3 Cd(C 2 O 4 )Cl(H 2 O)·H 2 O and BaCd(C 2 O 4 ) 1.5 Cl(H 2 O) 2 : Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties". Inorganic Chemistry. 63 (1): 67–72. doi:10.1021/acs.inorgchem.3c04154. ISSN 0020-1669. PMID 38112437. S2CID 266373131.
  30. ^ a b c d e f g h i j k Allouch, Hassan; Diop, Libasse (2012). "SYNTHESIS AND INFRARED STUDY OF SOME NEW SnC^sub 2^O^sub 4^Cl^sub 2^ ADDUCTS AND COMPLEXES". Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology, Food Industry. 13 (3): 317–323. ProQuest 1499908259.
  31. ^ a b c Zhang, Die; Wang, Qiang; Luo, Han; Cao, Liling; Dong, Xuehua; Huang, Ling; Gao, Daojiang; Zou, Guohong (March 2023). "Deep Eutectic Solvents Synthesis of A 2 Sb(C 2 O 4 )Cl 3 (A = NH 4 , K, Rb) with Superior Optical Performance". Advanced Optical Materials. 11 (6). doi:10.1002/adom.202202874. ISSN 2195-1071. S2CID 256156085.
  32. ^ a b c Price, Daniel J.; Powell, Annie K.; Wood, Paul T. (2003). "A new series of layered transition metal oxalates: hydrothermal synthesis, structural and magnetic studies". Dalton Transactions (12): 2478–2482. doi:10.1039/b301658g. ISSN 1477-9226.
  33. ^ Song, Yujie; Niu, Haoyu; Zeng, Zhuo; Jiang, Dequan; Liang, Youyuan; Huang, Hao; Xiao, Lixia; Xia, Zhengcai (September 2022). "The tuning of oxalato-bridge on magnetic interaction and field-induced phase transition in Ba2Co2Cl2(C2O4)3·4H2O". Journal of Magnetism and Magnetic Materials. 557: 169475. doi:10.1016/j.jmmm.2022.169475. S2CID 248877927.
  34. ^ Hölsä, Jorma; Koriseva, Eija (August 1991). "Thermal decomposition of LaC2O4Cl·3H2O : Eu3+: a high-resolution luminescence spectroscopy study". Thermochimica Acta. 185 (1): 25–33. doi:10.1016/0040-6031(91)80114-X.
  35. ^ Baker, P.; Smith, A. J. (1990-06-15). "Structure of lanthanum chloride oxalate trihydrate". Acta Crystallographica Section C Crystal Structure Communications. 46 (6): 984–985. Bibcode:1990AcCrC..46..984B. doi:10.1107/S0108270189009248. S2CID 98752634.
  36. ^ a b c d e f g Möbius, R.; Matthes, F. (June 1964). "Über die Verhältnisse beim Austausch von Oxalationen gegen Chloridionen bei Oxalathydraten der Seltenen Erden und des Yttriums". Zeitschrift für Chemie. 4 (6): 234–235. doi:10.1002/zfch.19640040618. ISSN 0044-2402.
  37. ^ Mulokozi, A. M.; Zuru, A. A. (November 1989). "Activation energy of thermal decomposition of fully dehydrated NdC2O4Cl·3H2O to NdOCl". Journal of Thermal Analysis. 35 (7): 2359–2366. doi:10.1007/BF01911900. ISSN 0368-4466. S2CID 95014944.
  38. ^ Mulokozi, A. M.; Weigel, F. (April 1975). "Characeriztion of Rare-Earth Metal Oxalato Halide-Hydrates by thermal analytical methods". Zeitschrift für anorganische und allgemeine Chemie. 414 (1): 62–68. doi:10.1002/zaac.19754140108. ISSN 0044-2313.
  39. ^ a b c Dunham, S. O.; Larsen, R. D.; Abbott, E. H. (November 1991). "Nuclear magnetic resonance investigation of the formation of oxalato, malonato, and 2-methylmalonato complexes of platinum(II). Crystal and molecular structures of potassium anti-bis(2-methylmalonato)platinate(II) dihydrate and potassium dichloro(oxalato)platinate(II) hydrate". Inorganic Chemistry. 30 (23): 4328–4335. doi:10.1021/ic00023a009. ISSN 0020-1669.
  40. ^ "K2[Pt(C2O4)Cl2]·H2O (K2Pt[C2O4]Cl2[H2O]) Crystal Structure - SpringerMaterials". materials.springer.com. Retrieved 2024-02-08.
  41. ^ a b c Yusenko, K. V.; Vasil’chenko, D. B.; Zadesenets, A. V.; Baidina, I. A.; Shubin, Yu. V.; Korenev, S. V. (October 2007). "Double complex salts [Pt(NH3)5Cl][M(C2O4)3] · nH2O (M = Fe, Co, Cr): Synthesis and study". Russian Journal of Inorganic Chemistry. 52 (10): 1487–1491. doi:10.1134/S0036023607100014. ISSN 0036-0236. S2CID 96549903.
  42. ^ Boudaren, Chaouki; Auffrédic, Jean-Paul; Louër, Michèle; Louër, Daniel (September 2003). "A powder X-ray diffraction study of lead chloride oxalate Pb 2 Cl 2 (C 2 O 4 ): ab initio structure determination and thermal behavior". Powder Diffraction. 18 (3): 205–213. doi:10.1154/1.1590352. ISSN 0885-7156. S2CID 98700786.
  43. ^ Staritzky, Eugene (28 August 1949). Optical and Morphological Crystallography of Plutonium Compounds (PDF). US Atomic Energy Commission. p. 34.
  44. ^ Arteaga, Ana; Nicholas, Aaron D.; Ducati, Lucas C.; Autschbach, Jochen; Surbella, Robert G. (2023-03-27). "Americium Oxalate: An Experimental and Computational Investigation of Metal–Ligand Bonding". Inorganic Chemistry. 62 (12): 4814–4822. doi:10.1021/acs.inorgchem.2c03976. ISSN 0020-1669. OSTI 1968457. PMID 36920249. S2CID 257534787.
  • v
  • t
  • e
Salts and covalent derivatives of the chloride ion
HCl He
LiCl BeCl2 B4Cl4
B12Cl12
BCl3
B2Cl4
+BO3 		C2Cl2
C2Cl4
C2Cl6
CCl4
+C
+CO3 		NCl3
ClN3
+N
+NO3 		ClxOy
Cl2O
Cl2O2
ClO
ClO2
Cl2O4
Cl2O6
Cl2O7
ClO4
+O 		ClF
ClF3
ClF5 		Ne
NaCl MgCl2 AlCl
AlCl3 		Si5Cl12
Si2Cl6
SiCl4 		P2Cl4
PCl3
PCl5
+P 		S2Cl2
SCl2
SCl4
+SO4 		Cl2 Ar
KCl CaCl
CaCl2 		ScCl3 TiCl2
TiCl3
TiCl4 		VCl2
VCl3
VCl4
VCl5 		CrCl2
CrCl3
CrCl4 		MnCl2
MnCl3 		FeCl2
FeCl3 		CoCl2
CoCl3 		NiCl2 CuCl
CuCl2 		ZnCl2 GaCl
GaCl3 		GeCl2
GeCl4 		AsCl3
AsCl5
+As 		Se2Cl2
SeCl2
SeCl4 		BrCl Kr
RbCl SrCl2 YCl3 ZrCl3
ZrCl4 		NbCl3
NbCl4
NbCl5 		MoCl2
MoCl3
MoCl4
MoCl5
MoCl6 		TcCl3
TcCl4 		RuCl2
RuCl3
RuCl4 		RhCl3 PdCl2 AgCl CdCl2 InCl
InCl2
InCl3 		SnCl2
SnCl4 		SbCl3
SbCl5 		Te3Cl2
TeCl2
TeCl4 		ICl
ICl3 		XeCl
XeCl2
XeCl4
CsCl BaCl2 * LuCl3 HfCl4 TaCl3
TaCl4
TaCl5 		WCl2
WCl3
WCl4
WCl5
WCl6 		ReCl3
ReCl4
ReCl5
ReCl6 		OsCl2
OsCl3
OsCl4
OsCl5 		IrCl2
IrCl3
IrCl4 		PtCl2
PtCl4 		AuCl
(Au[AuCl4])2
AuCl3 		Hg2Cl2
HgCl2 		TlCl
TlCl3 		PbCl2
PbCl4 		BiCl3 PoCl2
PoCl4 		AtCl Rn
FrCl RaCl2 ** LrCl3 RfCl4 DbCl5 SgO2Cl2 BhO3Cl Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaCl3 CeCl3 PrCl3 NdCl2
NdCl3 		PmCl3 SmCl2
SmCl3 		EuCl2
EuCl3 		GdCl3 TbCl3 DyCl2
DyCl3 		HoCl3 ErCl3 TmCl2
TmCl3 		YbCl2
YbCl3
** AcCl3 ThCl3
ThCl4 		PaCl4
PaCl5 		UCl3
UCl4
UCl5
UCl6 		NpCl3 PuCl3 AmCl2
AmCl3 		CmCl3 BkCl3 CfCl3
CfCl2 		EsCl2
EsCl3 		FmCl2 MdCl2 NoCl2
  • v
  • t
  • e
Salts of the oxalate ion
(H2C2O4) He
Li2C2O4 BeC2O4 +BO3 +CO3 (NH4)2C2O4
+NO3 		O F Ne
Na2C2O4
NaHC2O4 		MgC2O4 Al Si +PO4
+PO3 		+SO4 +Cl Ar
K2C2O4
KHC2O4 		CaC2O4 Sc Ti V CrC2O4 MnC2O4 FeC2O4
Fe2(C2O4)3
+Fe
humboldtine
+NH4 +Na +K +K 		CoC2O4 -Ni CuC2O4 Katsarosite Ga2(C2O4)3 Ge As Se Br Kr
Rb2C2O4 SrC2O4 Y2(C2O4)3 Zr Nb(HC2O4)5 Mo Tc Ru Rh Pd Ag2C2O4 CdC2O4 In2(C2O4)3 SnC2O4 Sb Te I Xe
Cs2C2O4 BaC2O4 * Lu2(C2O4)3 Hf Ta W Re Os Ir -Pt Au Hg Tl PbC2O4 Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(C2O4)3 Ce2(C2O4)3 Pr2(C2O4)3 Nd2(C2O4)3 Pm2(C2O4)3 Sm2(C2O4)3 Eu2(C2O4)3 Gd2(C2O4)3 Tb2(C2O4)3 Dy2(C2O4)3 Ho2(C2O4)3 Er2(C2O4)3 Tm2(C2O4)3 Yb2(C2O4)3
** Ac2(C2O4)3 Th(C2O4)2 Pa UO2C2O4 Np(C2O4)2 Pu(C2O4)2 Am Cm2(C2O4)3 Bk2(C2O4)3 Cf2(C2O4)3 Es2(C2O4)3 Fm Md No