Platinum(II) fluoride
Names | |
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Other names Platinum difluoride, difluoroplatinum | |
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Properties | |
Chemical formula | F2Pt |
Molar mass | 233.081 g·mol−1 |
Appearance | yellow crystals |
Solubility in water | insoluble |
Related compounds | |
Related compounds | Palladium difluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references |
Chemical compound
Platinum(II) fluoride is a binary chemical compound of platinum and fluorine with the chemical formula PtF
2.[1][2] Some sources claim that its existence is uncertain.[3][4]
Synthesis
Effect of fluorine on heated platinum wire at 500-600 °C:[5]
- Pt + F2 → PtF2
Physical properties
The compound forms yellow crystals. Insoluble in water.
Chemical properties
Platinum difluoride decomposes under strong heating:
- PtF2 → Pt + F2
References
- ^ "Platinum difluoride". NIST. Retrieved 3 May 2023.
- ^ Nikitin, M. I. (1 August 2008). "Thermal behavior of platinum fluorides: III. Platinum difluoride and trifluoride". Russian Journal of Inorganic Chemistry. 53 (8): 1292–1296. doi:10.1134/S0036023608080238. ISSN 1531-8613. S2CID 93184337. Retrieved 3 May 2023.
- ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3158. ISBN 978-0-412-30120-9. Retrieved 3 May 2023.
- ^ McAvoy, J.; Moss, K. C.; Sharp, D. W. A. (1 January 1965). "240. Phosphine and phosphite complexes of platinum(II) fluoride". Journal of the Chemical Society (Resumed): 1376–1379. doi:10.1039/JR9650001376. ISSN 0368-1769. Retrieved 3 May 2023.
- ^ "Journal of the Society of Chemical Industry". Society of Chemical Industry (Great Britain). Society of Chemical Industry.: 186 28 February 1890. Retrieved 3 May 2023.
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Platinum compounds
- Cs2Pt
- Pt(PPh3)4
- Pt(NH3)2(CO2)2C4H6
- cis-Pt(NH3)2Cl2
- trans-Pt(NH3)2Cl2
- K2Pt(CN)4
- Pt(NH3)4PtCl4
- Pt(NH3)2CO2CH2O
- (Cy(NH2)2)PtC2O4
- NH3PtCl2(PyrMe)
- Pt(OAc)2
- PtBr2
- PtCl2
- PtF2
- PtI
2 - PtP2
- K2PtCl4
- [(PtCl(NH3)2(C6H12(NH2)2))Pt(NH3)2](NO3)4
- Pt(OH)2
- PtSm
- Pt(C5H7O2)2
- PtS
Organoplatinum(II) compounds |
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- PtO2
- (NH4)2PtCl6
- H2PtCl6
- PtBr4
- PtCl4
- PtF4
- K2PtCl6
- Pt(OAc)2Cl2(NH3)(NH2Cy)
- Na2PtCl6
- Pt(OH)4
- PtI4
- PtS2
- PtSe2
- PtF5
- O2PtF6
- XePtF6
- PtF6